67862-38-8Relevant articles and documents
Novel Bonding Modes in Metallo-Dithiadiazolyl Complexes: Preparation and Crystal Structures of *MeCN and *2PhMe
Banister, Arthur J.,Gorrell, Ian B.,Lawrence, Simon E.,Lehmann, Christian W.,May, Iain,et al.
, p. 1779 - 1780 (1994)
Reaction of with in MeCN leads to *MeCN, which decomposes in toluene to give a novel trimetallic species, *2PhMe; the structures of both compounds are reported.
Electron Spin Resonance Study of CH3CNSSN, C6H5CNSSN, and SNSSN+ Free Radicals
Fairhurst, Shirley A.,Johnson, Karen M.,Sutcliffe, Leslie H.,Preston, Keith F.,Banister, Arthur J.,et al.
, p. 1465 - 1472 (1986)
Isotropic and powder e.s.r. spectra have been recorded for CH3CNSSN, C6H5CNSSN, and SNSSN+.Isotropic labelling with nitrogen-15 and sulphur-33 has been accomplished for SNSSN+ and it has been possible to prepare 33S15N33S33S15N+.Sulphur-33 satellites have been observed for C6H5CNSSN.MNDO and Gaussian 76 calculations have been used to calculate the minimum-energy structures of the radicals, while INDO calculations have provided values for the hyperfine coupling constants.Unfortunately, poor agreement was obtained between the latter and the corresponding experimental values.All the radicals dimerise in solution at low temperatures and we have been able to measure the energetics of dimerisation for C6H5CNSSN and SNSSN+.The dimers exist as crystalline solids which contain readily detectable amounts of the monomeric free radical.
Formation of thiazyl radicals by the thermolysis and photolysis of sulfur-nitrogen bicycles RCN5S3
Gritsan, Nina P.,Shuvaev, Konstantin V.,Kim, Stanislav N.,Knapp, Carsten,Mews, Rüdiger,Bagryansky, Victor A.,Zibarev, Andrey V.
, p. 204 - 206 (2008/03/12)
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