76843-75-9

Usage

Chemical class

Tetrazocine derivatives

Physical state

Yellow crystalline solid

Solubility

Insoluble in water, soluble in organic solvents

Potential applications

High-energy materials, explosives, building block in organic synthesis, pharmaceuticals

Fields of interest

Organic chemistry, material science

Structural properties

Unique structure

Chemical properties

Explosive properties, used in synthesis of various compounds

InChI:InChI=1/C14H10N4S2/c1-3-7-11(8-4-1)13-15-19-17-14(18-20-16-13)12-9-5-2-6-10-12/h1-10H/b15-13-,17-14u

Upstream product

• 24261-90-3 N,N,N'-tris(trimethylsilyl)benzamidine 
• 63481-05-0 4-phenyl-1,2-dithia-3,5-diazolium chloride 
• 67862-38-8 4-phenyl-1,2,3,5-dithiadiazolyl radical 
• 100-47-0 benzonitrile 
• 4039-32-1 lithium hexamethyldisilazane 
• 618-39-3 benzamidin 
• 6145-42-2 N,N-Dimethyl-guanidine 

Downstream Products

• 119273-52-8 4-Phenyl-1,2,3,5-dithiadiazolium-hexafluoroarsenat 
• 119273-53-9 3C₇H₅N₂S₂⁽¹⁺⁾*2AsF₆^(1-)*Cl^(1-) 
• 618-39-3 benzamidin 
• 110863-22-4 3,5-diphenyl-1,2,4,6-thiatriazine 1-oxide 
• 63481-05-0 4-phenyl-1,2-dithia-3,5-diazolium chloride 

Relevant academic research and scientific papers

Syntheses and Optoelectronic Properties of Planar Compounds 3,7-diaryl-1,5,2,4,6,8-dithiotetrazocine

Planar molecules 3,7-diaryl-1,5,2,4,6,8-dithiotetrazocines would be potential acceptor materials of organic solar cell because of their containing SN units. One-pot synthetic procedures of 3,7-diaryl-1,5,2,4,6,8-dithiotetrazocine compounds are developed t

Aryl 1,5-dithia-2,4,6,8-tetrazocines. A synthetic, electrochemical, and structural investigation

New preparative routes to the title compounds are reported in which the yields are substantially improved over previous methods.In one method, reaction of O2 with a mixture of XC6H4CN2S2(+)*Cl(-) and Ph3Sb leads to the products in 40-60percent yield.In an

Dithiatetrazocines and Dithiadiazolium Salts

Benzamidine and sulphur dichloride give the dithiadiazolium salt (2) as well as dithiatetrazocine (1), though better syntheses for both are reported; the first heterocyclic (7) and unsymmetrical (10) derivatives of dithiatetrazocine are described, and one dimethylamino substituent, in (10), is shown to be sufficient to destroy the planarity of the dithiatetrazocine ring.

Preparation of Dithiatetrazocines and Secondary Reactions

Li (1) or PhCN2(SiMe3)3 (3) react with SCl2 to give in good yields the dithiatetrazocine PhC(NSN)2CPh (2).By analogy, p-MeC6H4C(NSN)2CC6H4Me-p (7), p-NO2C6H4C(NSN)2CC6H4NO2-p (8), and p-CF3C6H4C(NSN)2CC6H4CF3-p (9) are obtained from the rea