67901-97-7

Upstream product

• 6380-23-0 3,4-dimethoxystyrene 
• 741719-67-5 (Z)-2-bromo-3-(3,4-dimethoxyphenyl)prop-2-enyl acetate 
• 741719-60-8 4-(2',2'-dibromocyclopropyl)-1,2-dimethoxybenzene 
• 741719-68-6 (Z)-2-bromo-3-(3,4-dimethoxyphenyl)prop-2-en-1-ol 
• 5720-07-0 4-methoxyphenylboronic acid 
• 741719-69-7 (E)-3-(3',4'-dimethoxyphenyl)-2-(4''-methoxyphenyl)prop-2-enyl acetate 

Relevant academic research and scientific papers

Utilization of 1-Aryl-2,2-dibromocyclopropanes in synthetic approaches to phenanthroquinolizidine and phenanthroindolizidine alkaloids

The 1-aryl-2,2-dibromocyclopropane 8 was treated with silver acetate in acetic acid to give the allylic acetate 19. Exposure of the derived chloride 26 to racemic 2-piperidinemethanol (7) then afforded the allylic amine 6, which engaged in a Pd(0)-catalyz