67915-63-3

Basic information

• Product Name: N-(2-HEPTYL)ANILINE
• Synonyms: Hexylamine,1-methyl-N-phenyl- (6CI); N-(1-Methylhexyl)aniline;N-(1-Methylhexyl)benzenamine
• CAS NO: 67915-63-3
• Molecular Formula: C₁₃H₂₁N
• Molecular Weight: 191.31
• Mol File: 67915-63-3.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 287.8°C at 760 mmHg
• Flash Point: 127.2°C
• Appearance: /
• Density: 0.918g/cm³
• Vapor Pressure: 0.00244mmHg at 25°C
• Refractive Index: 1.522
• CAS DataBase Reference: N-(2-HEPTYL)ANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-HEPTYL)ANILINE(67915-63-3)
• EPA Substance Registry System: N-(2-HEPTYL)ANILINE(67915-63-3)

Safety Data

• Hazardous Substances Data: 67915-63-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H21N/c1-3-4-6-9-12(2)14-13-10-7-5-8-11-13/h5,7-8,10-12,14H,3-4,6,9H2,1-2H3

Upstream product

• 56037-30-0 N-phenyl-(1-methylhexylidene)amine 
• 5609-09-6 3-hepten-2-one 
• 62-53-3 aniline 
• 110-43-0 n-pentyl methyl ketone 
• 104-15-4 toluene-4-sulfonic acid 
• 52390-72-4 2-Heptanol 
• 142-82-5 n-heptane 
• 98-95-3 nitrobenzene 
• 628-71-7 1-Heptyne 
• 592-76-7 1-Heptene 

Downstream Products

• 157363-63-8 N-(1-methylhexyl)-N-propylaniline 
• 157363-54-7 N-butyl-N-(1-methylhexyl)aniline 
• 56037-30-0 N-phenyl-(1-methylhexylidene)amine 

Relevant articles and documents

Construction of α-Alkylated Amines by Iridium Complex-Catalyzed One-Step Transfer Hydrogenation of C=C and C=N Bonds

Hydrogenation of C=C bond and reductive amination are important transformations utilized in chemistry. An environmentally friendly, efficient, and facile one-pot transfer hydrogenation of C=C bond of enones and reductive amination of C=N bond of imines are reported using iridium complex as catalysts and formic acid as hydrogen source in aqueous medium. In this catalytic system, a wide range of α-alkylated amines were obtained in excellent yields by one-pot transfer hydrogenation of C=C bond and reductive amination. The practical application of this protocol is characterized by gram-scale transformation.

Silver-catalyzed alkyne activation: The surprising ligand effect

An unexpected ligand effect was discovered in the silver(I)-catalyzed alkyne activation. For both aldehyde-alkyne-amine (A3) condensation and intermolecular alkyne hydroamination, the type B complex (P:Ag=1:1) effectively promoted the reaction, while no reaction occurred with either no ligand or excess ligands under the identical conditions.

Catalyst-free one-pot reductive alkylation of primary and secondary amines and N,N-dimethylation of amino acids using sodium borohydride in 2,2,2-trifluoroethanol

A simple and convenient procedure for the reductive alkylation of primary and secondary amines and N,N-dimethylation of amino acids is described using sodium borohydride as a reducing agent in 2,2,2- trifluoroethanol without use of a catalyst or any other additive. The solvent can be readily recovered from reaction products in excellent purity for direct reuse. Georg Thieme Verlag Stuttgart - New York.