679410-38-9Relevant academic research and scientific papers
[IrCl(cod)]2-catalyzed direct oxidative esterification of aldehydes with alcohols
Kiyooka, Syun-ichi,Wada, Yosuke,Ueno, Mahuyu,Yokoyama, Takeshi,Yokoyama, Reiko
, p. 12695 - 12701 (2008/03/14)
[IrCl(cod)]2 catalyzed the oxidative esterification of a variety of aldehydes with methanol as a solvent in combination with K2CO3 under mild conditions (rt, 12 h). The oxidative esterification reaction of aliphatic aldehydes also took place with olefinic alcohols as reagents in toluene under similar conditions.
The Ireland-Claisen rearrangement as a probe for the diastereoselectivity of nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group
Betson, Mark S.,Fleming, Ian
, p. 4005 - 4016 (2007/10/03)
The E- and Z-silyl enol ethers 4 derived from allyl 3-R-3-dimethyl(phenyl)silylpropanoate (R = Me, Pri and Ph) and the Z-silyl enol ethers 7 derived from 4-R-4-dimethyl(phenyl)silylbut-2-enyl acetate (R = Me and Pri) undergo Ireland-
