679437-92-4

Basic information

• Product Name: [((CH₂CH₂C)4CC)P(C₆H₅)(W(CO)5)]
• Synonyms: [((CH₂CH₂C)4CC)P(C₆H₅)(W(CO)5)]
• CAS NO: 679437-92-4
• Molecular Weight: 616.263
• Mol File: 679437-92-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [((CH₂CH₂C)4CC)P(C₆H₅)(W(CO)5)](CAS DataBase Reference)
• NIST Chemistry Reference: [((CH₂CH₂C)4CC)P(C₆H₅)(W(CO)5)](679437-92-4)
• EPA Substance Registry System: [((CH₂CH₂C)4CC)P(C₆H₅)(W(CO)5)](679437-92-4)

Safety Data

• Hazardous Substances Data: 679437-92-4(Hazardous Substances Data)

Upstream product

• 82265-64-3 syn-[5,6-dimethyl-2,3-bis(methoxycarbonyl)-7-phenyl-7-phosphanorbornadiene]pentacarbonyltungsten 
• 82888-50-4 (phenylphosphinidene)pentacarbonyltungsten 
• 136504-44-4 7,7'-Bi(dispiro<2.0.2.1>heptyliden) 

Downstream Products

• 29890-05-9 tetracarbonyl-1,2-bis(diphenylphosphino)ethane-tungsten(0) 
• 679437-96-8 [W(CO)5P(C₆H₅)(C(CH₂CH₂)C(CH₂CH₂)CC(CH₂CH₂)C(CH₂CH₂)C)] 

Relevant articles and documents

Branched Phospha[7]triangulanes

A highly strained, thermally stable (up to 150 °C) branched phospha[7]triangulane was synthesized from the second-generation bicyclopropylidene and transient phosphinidene [Ph?P=W(CO)5], followed by demetalation in refluxing xylene. Bulkier transient CuCl?alkene-complexed phosphinidene gave 2-phosphabicyclo-[3.2.0]hept-1(5)-ene as an additional product. The "outer sphere" spirocyclopropanes provide a stabilizing factor for both of these novel compounds. Copyright