679812-24-9

Upstream product

• 862670-46-0 (2R,3R)-2-Benzyloxy-5-(4-methoxy-benzyloxy)-3-methyl-pentan-1-ol 
• 158817-23-3 (2R,3R)-5-p-methoxybenzyloxy-3-methylpentane-1,2-diol 
• 146986-42-7 ((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl) oxiran-2-yl)methanol 
• 100-52-7 benzaldehyde 

Downstream Products

• 862670-52-8 Benzoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-vinyl-tetrahydro-furan-3-yl ester 
• 862670-58-4 Benzoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-hydroxymethyl-tetrahydro-furan-3-yl ester 
• 679812-26-1 (2R,3R,5S)-5-((2R,3R,4R)-3-Benzyloxy-2-methoxy-4-methyl-tetrahydro-pyran-2-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-ol 
• 862670-60-8 Benzoic acid (2R,3R,5S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-((2S,3R,4R)-3-hydroxy-2-methoxy-4-methyl-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester 
• 862670-59-5 Benzoic acid (2R,3R,5S)-5-((2R,3R,4R)-3-benzyloxy-2-methoxy-4-methyl-tetrahydro-pyran-2-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester 
• 862670-51-7 Benzoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester 
• 862670-61-9 (2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-2-methyl-heptanoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-vinyl-tetrahydro-furan-3-yl ester 

Relevant academic research and scientific papers

Synthesis of the common left-half part of pectenotoxins

The common left-half [C31-C33(OC1-C7)-C40] part of pectenotoxins has been synthesized convergently from the C31-C35, C36-C40, and C1-C7 parts. The C31-C35 part, prepared via a new route shorter than our previous route, was coupled with the C36-C40 part through reductive lithiation and addition reactions to give an adduct stereoselectively, which was converted to a cyclic acetal corresponding to the C31-C40 part. The left-half was synthesized by a three-step process including esterification of the C31-C40 part with the C1-C7 part.