680-88-6Relevant academic research and scientific papers
NICKEL CHLORIDE CATALYZED REARRANGEMENT OF ALLYLIC PHOSPHITES
Lu, Xiyan,Zhu, Jingyang
, p. 239 - 244 (1986)
Allylic phosphites can be rearranged to the corresponding allylic phosphonates under the catalysis of nickel chloride.Dienes and dialkyl phosphonates are formed by an elimination reaction when there is hydrogen atom at the β-position of the carbon-metal bond in the allylic intermediate.The mechanisms of these reactions are discussed.
