Journal of Organometallic Chemistry p. 239 - 244 (1986)
Update date:2022-08-04
Topics:
Lu, Xiyan
Zhu, Jingyang
Allylic phosphites can be rearranged to the corresponding allylic phosphonates under the catalysis of nickel chloride.Dienes and dialkyl phosphonates are formed by an elimination reaction when there is hydrogen atom at the β-position of the carbon-metal bond in the allylic intermediate.The mechanisms of these reactions are discussed.
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