68001-60-5Relevant articles and documents
Reactions of areneselenenamides with alkenes in the presence of phosphorus(V) and sulfur(IV) oxyhalides. New synthesis of β-Haloalkyl Selenides
Antipin,Klak,Beloglazkina,Zyk
experimental part, p. 842 - 847 (2009/12/09)
A new procedure was proposed for activation of areneselenenamides with phosphorus(V) and sulfur (IV) oxyhalides. According to the 1H, 13C, and 31P NMR data, areneselenenamide reacts with phosphorus oxyhalide to form interm
Mechanistic Studies on the Addition Reactions of Benzeneselenenyl Bromide to Substituted Styrenes
Luh, Tien-Yau,So, Wang-Hung,Cheung, Kam Shing,Tam, Shang Wai
, p. 3051 - 3053 (2007/10/02)
Second-order kinetics of the addition of benzeneselenenyl bromide to seven substituted styrenes was studied.The ρ and ρ+ values were -0.37 and -0.27, respectively.The mechanism were discussed and the product distributions were found to be strongly solvent dependent. 1H, 13C, as wel as 77Se NMR spectra were employed for product identification.The correlation between 77Se NMR shifts for the adducts 1 and 2 ? values were presented.