680218-11-5

Upstream product

• 186581-53-3 diazomethane 
• 217467-50-0 (1S,7S)-1,8,8-trimethyl-2-oxabicyclo[5.4.0]undecan-3-one 
• 60134-39-6 (-)-(4aS,8aS)-3,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalen-1(2H)-one 
• 67-56-1 methanol 

Downstream Products

• 680218-13-7 methyl 2-[2-((1S,2S)-2-hydroxy-2,6,6-trimethylcyclohexyl)ethyl]-3-hydroxybutanoate 
• 680218-17-1 2-[2-((1S,2S)-2-hydroxy-2,6,6-trimethylcyclohexyl)ethyl]-3-hydroxybutyl 4-methylbenzenesulfonate 
• 680218-19-3 2-[2-((1S,2S)-2-hydroxy-2,6,6-trimethylcyclohexyl)ethyl]-3-oxobutyl 4-methylbenzenesulfonate 
• 145631-62-5 3-[2-((2S)-2-hydroxy-2,6,6-trimethylcyclohexyl)ethyl]but-3-en-2-one 
• 680218-15-9 2-[2-((1S,2S)-2-hydroxy-2,6,6-trimethylcyclohexyl)ethyl]butane-1,3-diol 
• 771531-59-0 4-((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-butyric acid methyl ester 
• 771531-57-8 (1S,2S)-2-Allyl-1,3,3-trimethyl-cyclohexanol 
• 771531-79-4 2-Phenylselanyl-4-((1S,6S)-2,2,6-trimethyl-6-trimethylsilanyloxy-cyclohexyl)-butyric acid methyl ester 
• 771531-80-7 ((1S,2S)-2-Allyl-1,3,3-trimethyl-cyclohexyloxy)-trimethyl-silane 
• 771531-61-4 ((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde 

Relevant academic research and scientific papers

An Efficient Alternative Synthesis of (+)-(6S,7S)-7-Hydroxy-6,11-cyclofarnes-3(15)-en-2-one, the (S)-Enantiomer of the Antibacterial Sesquiterpene from Premna oligotricha

The title compound has been synthesized from optically active lactone derived from (S)-(+)-Wieland-Miescher ketone analogue employing solid-state Baeyer-Villiger reaction.

Novel stereocontrolled approach to syn- and anti-oxepene-cyclogeranyl trans-fused polycyclic systems: Asymmetric total synthesis of (-)-Aplysistatin, (+)-Palisadin A, (+)-Palisadin B, (+)-12-hydroxy-Palisadin B, and the AB ring system of adociasulfate-2 a

A new stereocontrolled method for the formation of trans-anti cyclogeranyl-oxepene systems is described. The demanding stereochemistry is secured by stereoselective coupling of a cyclogeranyl tertiary alcohol with a 1,2-unsymmetrically substituted epoxide