68069-67-0

Basic information

• Product Name: Bicyclo[2.2.2]oct-5-en-2-one, (1S)-
• CAS NO: 68069-67-0
• Molecular Formula: C8H10O
• Molecular Weight: 122.167
• Mol File: 68069-67-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.2]oct-5-en-2-one, (1S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.2]oct-5-en-2-one, (1S)-(68069-67-0)
• EPA Substance Registry System: Bicyclo[2.2.2]oct-5-en-2-one, (1S)-(68069-67-0)

Safety Data

• Hazardous Substances Data: 68069-67-0(Hazardous Substances Data)

Downstream Products

• 500-23-2 bicyclo<2.2.2>-octa-2,5-diene 
• 106988-59-4 (1S,4R,5R,6R)-6-Chloro-5-p-tolylsulfanyl-bicyclo[2.2.2]octan-2-one 
• 106988-60-7 (exo-5,endo-6)-6-Chloro-5-p-tolylsulfinylbicyclo<2.2.2>octan-2-one 
• 6688-07-9 5-hydroxybicyclo[2.2.2]oct-2-ene 
• 6688-07-9 hydroxy-5 exo bicyclo<2.2.2>octene-2 
• 2716-23-6 bicyclo[2.2.2]octan-2-one 
• 40335-86-2 (+)-Bicyclo<2.2.2>octan-2-ol 
• 89207-69-2 (1S,4aR,4bS)-1-[2-(3-Methoxy-phenyl)-ethyl]-hexahydro-cyclopropa[cd]pentalen-2-one 
• 24480-76-0 1-(3'-cyclohexenyl)-3-phenyl-2-propanone 
• 18955-93-6 1-(2'-cyclohexenyl)-2-propanone 
• 24476-16-2 1-(3'-cyclohexenyl)-2-propanone 
• 94064-42-3 Bicyclo[2.2.2]octanon-⁽²⁾-p-toluolsulfonylhydrazonn 
• 931-64-6 norbornene 

Relevant articles and documents

Fragmentation of Homoallylic Alkoxides. Thermolysis of Potassium 2-Substituted Bicyclooct-5-en-2-alkoxides

Thermolysis of the potassium 2-substituted bicyclooct-5-en-2-alkoxides derived from alcohols 2-17 at 90-120 deg C in hexamethylphosphoric triamide affords unsaturated ketones resulting from allylic bond cleavage.The mechanistic and synthetic aspects of this anionic fragmentation are discussed with reference to the formation of 1-(3'-cyclohexenyl)-2-alkanones 18-28 via initial heterolytic C(1),C(2)-bond cleavage in the substrate alkoxide and regioselective, intramolecular protonation of the resultant transient allylic anion.