68089-93-0Relevant academic research and scientific papers
Reaction of Dicyano Epoxides with Thiocyanate Ion: Route to α-Thiocyanato Derivatives or to 2-Acetylimino-1,3-oxathioles and X-Ray Crystal Structure of 2-Acetylimino-4-(4-tolyl)-1,3-oxathiole-5-carbonitrile
Marechal, Alenka Majcen Le,Robert, Albert,Leban, Ivan
, p. 351 - 356 (2007/10/02)
β-Aryl dicyano epoxides reacted as synthetic equivalents of ketene dications with KSCN in aq. dimethyl sulfoxide or EtOH, or with NH4SCN in acetonitrile, to give α-thiocyanato derivatives.When Ac2O was used as a solvent, the 1,3-oxathiolane intermediates
