681222-90-2

Upstream product

• 87326-88-3 methyl 6-deoxy-6-iodo-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside 
• 106-95-6 allyl bromide 

Downstream Products

• 1197981-42-2 1D-(1,2,4,5/3)-4-O-allyl-2,3-di-O-benzyl-1-O-methyl-5-hydroxycyclohexanepentol 
• 1197981-40-0 1D-(1,2,4/3,5)-4-O-allyl-2,3-di-O-benzyl-1-O-methyl-5-hydroxycyclohexanepentol 
• 681222-98-0 (2S,3R,4S,5S)-2-allyloxy-3,4-dibenzyloxy-5-methyloxycyclohexanone 

Relevant academic research and scientific papers

Synthesis of neamine-derived pseudodisaccharides by stereo- and regio-selective functional group transformations

Neamine is normally found as a core structure of aminoglycoside antibiotics. In order to understand the relationship between the antibiotic activity and the configurations of the functional groups of neamine, a series of novel neamine analogues with funct

Trimethylaluminium promoted rearrangements of unsaturated sugars into cyclohexanes

Trimethylaluminium induces a stereoselective rearrangement of unsaturated glycosides into polyfunctionalised cyclohexanic rings containing a tertiary alcohol and retaining the anomeric group. In contrast with the previously used triisobutylaluminium, no de-O-benzylation reaction was observed.