681222-98-0Relevant academic research and scientific papers
Trimethylaluminium promoted rearrangements of unsaturated sugars into cyclohexanes
Jia, Cai,Pearce, Alan J.,Bleriot, Yves,Zhang, Yongmin,Zhang, Li-He,Sollogoub, Matthieu,Sinay, Pierre
, p. 699 - 703 (2004)
Trimethylaluminium induces a stereoselective rearrangement of unsaturated glycosides into polyfunctionalised cyclohexanic rings containing a tertiary alcohol and retaining the anomeric group. In contrast with the previously used triisobutylaluminium, no de-O-benzylation reaction was observed.
