68157-44-8Relevant academic research and scientific papers
Reaction of alkoxycarbene complexes of tungsten with 1,2-dihydroquinoline: Single vs. double hydride transfers to the carbene-carbon: Synthesis, X-ray structure and reactivity of a quinolinium ylide complex of tungsten pentacarbonyl
Rudler,Alvarez,Denise,Parlier,Vaissermann
, p. 105 - 112 (2003)
The more stable dihydropyridine, 1,2-dihydroquinoline (2), reacts with carbene complex of tungsten (CO)5W=(OEt)Ph (3) to give the expected quinolinium complex 4, fully characterized by an X-ray structure. By contrast, under the same conditions
The Chemistry of N-Substituted Benzotriazoles; Part 11. The preparation of Tertiary Amines Containing Tertiary-Alkyl Groups from Ketones, Secondary Amines, and Organometallic Reagents
Katritzky, Alan R.,Najzarek, Zbigniew,Dega-Szafran, Zofia
, p. 66 - 69 (2007/10/02)
The preparation of important pharmaceutically active highly branched tertiary amines by the reaction of Grignard reagents with adducts of cyclic ketones, benzotriazole (or pyrazole) and secondary amines is far superior to previously available routes.
