68175-34-8

Basic information

• Product Name: Benzene, 1-(1,1-dimethylethyl)-4-(1-propenyl)-
• CAS NO: 68175-34-8
• Molecular Formula: C13H18
• Molecular Weight: 174.286
• Mol File: 68175-34-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,1-dimethylethyl)-4-(1-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,1-dimethylethyl)-4-(1-propenyl)-(68175-34-8)
• EPA Substance Registry System: Benzene, 1-(1,1-dimethylethyl)-4-(1-propenyl)-(68175-34-8)

Safety Data

• Hazardous Substances Data: 68175-34-8(Hazardous Substances Data)

Upstream product

• 67081-98-5 (+/-)-1-<4-(trifluoromethyl)phenyl>-1-propanol 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 1746-23-2 4-tert-Butylstyrene 
• 43084-97-5 tert-butyl perester of 4-methoxybenzoic acid 
• 22313-60-6 tert-butyl 4-methylbenzoperoxoate 
• 2123-93-5 tert-butyl 3-phenylpropaneperoxoate 
• 107-71-1 tert-butyl peroxyacetate 
• 614-45-9 tert-Butyl peroxybenzoate 
• 1160175-48-3 tertiary-butyl peroxy cyclopentyl carbonate 
• 2372-21-6 OO-tert-butyl O-isopropyl monoperoxycarbonate 
• 69945-22-8 tertiary-butyl peroxy butyl carbonate 
• 61040-16-2 t-butylperoxyphenyl monocarbonate 
• 34443-12-4 OO-tert-butyl O-(2-ethylhexyl) monoperoxycarbonate 

Downstream Products

• 84434-23-1 3-(4-(tert-butyl)phenyl)acrylaldehyde 
• 81561-77-5 1-[4-(1,1-dimethylethyl)phenyl]propan-2-one 
• 1621020-12-9 C₁₃H₁₉F 
• 1285188-17-1 1-(tert-butyl)-4-(2-chloropropyl)benzene 
• 136027-29-7 1-(4-t-butylphenyl)-propan-2-amine 

Relevant articles and documents

Regioselective differentiation of vicinal methylene C-H bonds enabled by silver-catalysed nitrene transfer

Silver-catalyzed nitrene insertion enables the formation of benzosultams in good yield and with regioselectivity complementary to other transition metal nitrene-transfer catalysts. Preferential formation of six-membered benzosultam rings predominates for alkyl-substituted benzenesulphonamide precursors. Ligand-controlled tunability is also achieved for benzenesulphonamides with γ-branched alkyl substituents. Mechanistic probes suggest that the reaction pathway differs depending on whether a α (benzylic) or β (homobenzylic) C-H bond undergoes amidation, as well as the catalyst identity.

Visible-light-mediated anti-regioselective nitrone 1, 3-dipolar cycloaddition reaction and synthesis of bisindolylmethanes

The development of photoredox reactions of 1, 3- dipolar cycloaddition of nitrones with alkenes is reported. It offers an efficient synthetic method to obtain isoxazolidine derivatives under mild conditions in synthetically useful yields. The nitrones are cyclized with oxidizable styrenes and aliphatic alkenes via a polar radical crossover cycloaddition reaction through photocatalytic reaction without additives. In addition, bis(indole)methanes can also be prepared through this method.

Alkene Oxyalkylation Enabled by Merging Rhenium Catalysis with Hypervalent Iodine(III) Reagents via Decarboxylation

Rhenium-catalyzed oxyalkylation of alkenes is described, where hypervalent iodine(III) reagents derived from widely occurring aliphatic carboxylic acids were used as, for the first time, not only an oxygenation source but also an alkylation source via decarboxylation. The reaction also features a wide substrate scope, totally regiospecific difunctionalization, mild reaction conditions, and ready availability of both substrates. Mechanistic studies revealed a decarboxylation/radical-addition/cation-trapping cascade operating in the reaction.