6824-61-9

Basic information

• Product Name: 7,8,9,10-Tetrahydro-1,6,7,8,11-pentahydroxy-8-methyl-5,12-naphthacenedione
• Synonyms: 7,8,9,10-Tetrahydro-1,6,7,8,11-pentahydroxy-8-methyl-5,12-naphthacenedione
• CAS NO: 6824-61-9
• Molecular Formula: C19H16O7
• Molecular Weight: 356.33
• Mol File: 6824-61-9.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 7,8,9,10-Tetrahydro-1,6,7,8,11-pentahydroxy-8-methyl-5,12-naphthacenedione(CAS DataBase Reference)
• NIST Chemistry Reference: 7,8,9,10-Tetrahydro-1,6,7,8,11-pentahydroxy-8-methyl-5,12-naphthacenedione(6824-61-9)
• EPA Substance Registry System: 7,8,9,10-Tetrahydro-1,6,7,8,11-pentahydroxy-8-methyl-5,12-naphthacenedione(6824-61-9)

Safety Data

• Hazardous Substances Data: 6824-61-9(Hazardous Substances Data)

Upstream product

• 95384-67-1 (RS)-2-(9,10-Dihydro-1-hydroxy-4,8-dimethoxy-9,10-dioxo-2-anthrylmethyl)-3-oxobuttersaeure-ethylester 
• 88101-11-5 1-Hydroxy-4,8-dimethoxy-2-(3-oxobutyl)-9,10-anthrachinon 
• 88100-90-7 (RS)-2-(4,4-Dichlor-3-hydroxy-3-methylbutyl)-1,4,8-trihydroxy-9,10-anthrachinon 
• 88100-93-0 1,4,8-Trihydroxy-2-(3-oxobutyl)-9,10-anthrachinon 
• 75963-94-9 3-Chlormethyl-4-hydroxy-1,5-dimethoxy-9,10-anthrachinon 
• 88210-99-5 (RS)-2-Formyl-3,4-dihydro-6,11-dihydroxy-2-methyl-2H-anthra<1,2-b>pyran-7,12-dion 
• 88101-10-4 (RS)-2-(9,10-Dihydro-1-hydroxy-4,8-dimethoxy-9,10-dioxo-2-anthrylmethyl)-3-oxocapronsaeure-ethylester 
• 88100-92-9 (RS)-2-(3-Dichlormethyl-3-hydroxyhexyl)-1,4,8-trihydroxy-9,10-anthrachinon 
• 88101-12-6 1-Hydroxy-4,8-dimethoxy-2-(3-oxohexyl)-9,10-anthrachinon 
• 88100-94-1 1,4,8-Trihydroxy-2-(3-oxohexyl)-9,10-anthrachinon 
• 88101-20-6 cis-7,8,9,10-Tetrahydro-1,6,7,8,11-pentahydroxy-8-propyl-5,12-naphthacenchinon 
• 67-64-1 acetone 
• 115860-91-8 2-Ethyl-2-hydroxy-4-(1,4,8-trihydroxy-9,10-dioxo-9,10-dihydro-anthracen-2-yl)-butyraldehyde 
• 72818-12-3 cis-3a,4,5,13b-Tetrahydro-6,8,13-trihydroxy-2,2,3a-trimethylnaphthaceno<1,2-d>-1,3-dioxol-7,12-dion 

Downstream Products

• 21204-31-9 rac-α₁-rhodomycinone 

Relevant articles and documents

SYNTHETIC ANTHRACYCLINONES-XXVII. ANTHRACYCLINONES BY INTRAMOLECULAR MARSCHALK REACTION. SYNTHESIS OF THE FEUDOMYCINONES AND RHODOMYCINONES.

1,4,5-Trihydroxy-9,10-anthraquinone is transformed regioselectively to the α-hydroxy dichlorides 18-21, which are cyclized to yield predominantely the naturally configurated 9,10-trans-diols 1,3,26, and 27 (80 to 96percent d.e.).The monotrifluoroacetates 38-40 derived from the trans-diols are hydroxylated via bromination at C-7 to yield almost exclusively the 7,9-cis-9,10-trans-triols α1-rhodomycinone (4), feudomycinone D (7), and 4-O-methyl-β-rhodomycinone (42).The feudomycinones A (5) and C (6) are obtained with less chemo- and stereoselectivity by hydroxylation of the 10-deoxycompounds 33 and 34.