68298-07-7Relevant academic research and scientific papers
Study of unusually high rotational barriers about S-N bonds in nonafluorobutane-1-sulfonamides: The electronic nature of the torsional effect
Lyapkalo, Ilya M.,Reissig, Hans-Ulrich,Schaefer, Andreas,Wagner, Armin
, p. 4206 - 4215 (2002)
Slow rotation about the S-N bond in N,N-disubstituted nonafluorobutane-1-sulfonamides 1 can easily be detected by NMR measurements at room temperature. This effect causes magnetic nonequivalence of otherwise identical geminal substituents in symmetrical s
Rhodium-catalyzed intermolecular C-H amination of simple hydrocarbons using the shelf-stable nonafluorobutanesulfonyl azide
Suarez, Jose Ramon,Chiara, Jose Luis
supporting information, p. 9194 - 9196 (2013/09/24)
A new procedure has been developed for the direct intermolecular C-H amination of simple hydrocarbons using shelf-stable nonafluorobutanesulfonyl azide in the presence of a dirhodium(ii) tetracarboxylate catalyst under mild reaction conditions. Some mechanistic details are briefly discussed on the basis of control experiments.
