6830-31-5

Basic information

• Product Name: Piperazine, 1,4-dichloro- (6CI,7CI,9CI)
• Synonyms: Piperazine, 1,4-dichloro- (6CI,7CI,9CI);1,4-DICHLORO-PIPERAZINE
• CAS NO: 6830-31-5
• Molecular Formula: C₄H₈Cl₂N₂
• Molecular Weight: 155.03
• Product Categories: PIPERIDINE
• Mol File: 6830-31-5.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Piperazine, 1,4-dichloro- (6CI,7CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Piperazine, 1,4-dichloro- (6CI,7CI,9CI)(6830-31-5)
• EPA Substance Registry System: Piperazine, 1,4-dichloro- (6CI,7CI,9CI)(6830-31-5)

Safety Data

• Hazardous Substances Data: 6830-31-5(Hazardous Substances Data)

Upstream product

• 280-57-9 1,4-diaza-bicyclo[2.2.2]octane 
• 110-85-0 piperazine 

Downstream Products

• 1225463-78-4 1,4-bis(5-phenyl-1,3,4-oxadiazol-2-yl)piperazine 
• 613-39-8 1,4-diphenyl-piperazine 

Relevant articles and documents

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Poly(N,N′-dichloro-N-ethylbenzene-1,3-disulfonamide) and N,N,N′,N′-tetrachlorobenzene-1,3-disulfonamide as novel reagents for the synthesis of N-chloroamines, nitriles and aldehydes

The applications of poly(N,N′-dichloro-N-ethylbenzene-1,3- disulfonamide) (PCBS) and N,N,N′,N′-tetrachlorobenzene-1,3- disulfonamide (TCBDA) as novel reagents for the preparation of N,N-dichloroamines, nitriles, and aldehydes from primary amines under various conditions are described. Also, a simple and effective procedure for the direct oxidative conversion of primary alcohols into nitriles was successfully carried out with TCBDA and PCBS in aqueous ammonia. Georg Thieme Verlag Stuttgart.

Studies on the Ethylhydroperoxide-Supported Oxidation of 1,4-Diazabicyclooctane by Chloroperoxidase

The chloroperoxidase-catalyzed oxidation of 1,4-diazabicyclooctane (DABCO) by H2O2 or ethylhydroperoxide (EHP) in the presence of Cl- was investigated at pH 2.75, 5.0, and 7.0, and the results were compared with those of the chemical oxidation by HOCl.The oxidation of DABCO in the chloroperoxidase-EHP-Cl- system at pH 5.0 gave a fairly well-resolved elctron spin resonance spectrum, which was identified as that of the radical cation of DABCO.The dectection of the radical cation suggests that the first step of the chloroperoxidase-catalyzed oxidation of DABCO is the formation of the DABCO chloroammonium cation followed by the homolysis of the cation.Keywords-chloroperoxidase; ESR; ethylhydroperoxide; 1,4-diazabicyclooctane; DABCO cation radical; ethylhydroperoxide-supported oxidation; hypochlorous acid; triethylenediamine