683271-28-5Relevant academic research and scientific papers
The Synthesis of New C2-Symmetric Chiral 1,4-Diamino Motif and Application in Catalytic Asymmetric Alkynylation of meso-Epoxides
Zhu, Chengjian,Yang, Minghua,Sun, Jiangtao,Zhu, Yuhua,Pan, Yi
, p. 465 - 468 (2004)
The efficient asymmetric preparation of the C2-symmetric chiral 1,4-diamine, (1R,2S,4R,5S)-1,4-diamino-2,5-dimethylcyclohexane (5), and its salen ligands is described. With the Mitsunobu reaction as the key step, the overall yield of the four-s
Synthesis of novel 1,4-bissulfonamide ligands for enantioselective addition of diethylzinc to aldehydes
Yang, Minghua,Sun, Jiangtao,Zhu, Chengjian
, p. 1697 - 1702 (2012/01/13)
Several novel chiral sulfonamide ligands based on (1R,2S,4R,5S)-1,4- diamino-2,5-dimethylcyclohexane skeleton have been synthesized and their application in the enantioselective addition of diethylzinc to aldehydes was investigated in the presence of Ti(O
