68388-24-9Relevant academic research and scientific papers
Intramolecular azide-alkene 1,3-dipolar cycloaddition/enamine addition(s) cascade reaction: Synthesis of nitrogen-containing heterocycles
De Miguel, Irene,Herradon, Bernardo,Mann, Enrique
, p. 1731 - 1736 (2012/07/28)
A cascade intramolecular azide-alkene 1,3-dipolar cycloaddition/1,2 enamine and/or 1,4 enamine addition reaction sequence has been developed, and provides access to a variety of nitrogen containing heterocycles from readily available ω-azido alkenes. Copy
A chemoselective reduction of alkynes to (E)-alkenes
Trost, Barry M.,Ball, Zachary T.,Joege, Thomas
, p. 7922 - 7923 (2007/10/03)
The trans reduction of all types of alkynes to give (E)-olefins is achieved through a two-stage trans hydrosilylation and protodesilylation. Reaction of an alkyne and a silane with the ruthenium catalyst [Cp*Ru(MeCN)3]PF6 results in
Fe(III)/Cu(II) mediated 5- and 6-exo oxidative ring expansion/cyclisation of cyclopropyl ethers: Studies towards dictyol C and α-eudesmol
Booker-Milburn, Kevin I.,Cox, Brian,Grady, Mick,Halley, Frank,Marrison, Shaun
, p. 4651 - 4655 (2007/10/03)
The outcome of oxidative ring expansion/cyclisation of cyclopropanes with a mixed Fe(III)/Cu(II) system was found to be dependent on the mode of cyclisation. When 6-exo cyclisation was attempted unusual products resulting from oxidation of ring opened primary radicals were obtained. (C) 2000 Elsevier Science Ltd.
THE VINYLOGOUS CONIA REARRANGEMENT : A MASKED ENE REACTION
Kende, Andrew S.,Newbold, Ronald C.
, p. 4329 - 4332 (2007/10/02)
A novel carbocyclic thermal rearrangement of 4-substituted 2-cyclohexen-1-ones is suggested to involve a 'masked' ene reaction and provides a facile route to spirocyclic cyclohexenone systems.
