684284-12-6 Usage
General Description
(-)-Camphanyldimethylchlorosilane is a chemical compound that is commonly used in the synthesis of organic and pharmaceutical compounds. It is a chlorosilane derivative of camphene, a naturally occurring bicyclic monoterpene. This chemical is used as a reagent in the production of silicon-containing polymers and in the modification of surfaces to impart hydrophobic or oleophobic properties. In addition, (-)-camphanyldimethylchlorosilane has been employed in the preparation of functionalized silanes for use in organic and inorganic chemistry, as well as in the semiconductor industry. Overall, this compound plays a crucial role in various chemical applications, particularly in the development of new materials and pharmaceuticals.
Check Digit Verification of cas no
The CAS Registry Mumber 684284-12-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,8,4,2,8 and 4 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 684284-12:
(8*6)+(7*8)+(6*4)+(5*2)+(4*8)+(3*4)+(2*1)+(1*2)=186
186 % 10 = 6
So 684284-12-6 is a valid CAS Registry Number.
684284-12-6Relevant articles and documents
Chiral organochlorosilanes derived from terpenes: Diastereoselective hydrosilylation of methylene bicyclo[2.2.1]heptanes with HSiMenCln-2 (n = 0-2)
Beckmann, Jens,Dakternieks, Dainis,Duthie, Andrew,Floate, Susan L.,Foitzik, Richard C.,Schiesser, Carl H.
, p. 909 - 916 (2007/10/03)
The H2PtCl6 catalysed hydrosilylation of the terpenes (+)-α-fenchene (XI), (-)-2-methylene bornane (XII), (+)-camphene (XIII) and (-)-3-methylene fenchane (XIV) using HSiMe2Cl or HSiMeCl2 proceeds with high regioselectively and in some cases, with high diastereoselectivity. KF-assisted oxidation of the hydrosilylation products gives predominately endo-terpene alcohols. The alcohols have inverted endo/exo ratios to those formed by oxidative hydroboration. Reaction of XIV with HSiMe2Cl or HSiMeCl2 is accompanied by a clean rearrangement of the isocamphane skeleton into (+)-2-methylene bornane (XII) prior to hydrosilylation.
