68469-62-5Relevant articles and documents
Intramolecular radical hydrosilylation - The first radical 5-endo-dig cyclisation
Amrein, Stephan,Studer, Armido
, p. 1592 - 1593 (2007/10/03)
Intramolecular radical hydrosilylations using allyloxy- and propargyloxycyclohexadienylsilanes comprising 5-endo-trig as well as 5-endo-dig processes are presented.
The γ-silicon effect on solvolyses of the 3-(aryldimethylsilyl)propyl system
Fujio, Mizue,Nakashima, Tohru,Fujiyama, Ryoji,Kim, Hyun-Joong,Tsuno, Yuho
, p. 612 - 615 (2007/10/03)
The γ-silicon effects in solvolyses were studied mechanistically on 3-(aryldimethylsilyl)propyl tosylates in various solvents based on the substituent effects. The mechanism can be described as competing reactions of the γ-silyl-assisted (kSi) and the solvent-assisted (ks) pathways. Copyright
The Regiochemistry and Stereochemistry of the Hydroboration of Allylsilanes
Fleming, Ian,Lawrence, Nicholas J.
, p. 3309 - 3326 (2007/10/02)
The hydroboration of a wide range of allylsilanes 3 and 5-21 is found to be generally regioselective for attachment of the boron to C-3 and hydrogen to C-2 of the allyl unit, and to be generally stereoselective in the sense 1, with attachment of the boron
