68592-35-8Relevant academic research and scientific papers
UNUSUAL REACTIVITY OF NORBORNANE BRIDGEHEAD DERIVATIVES
Martinez, A. Garcia,Vilar, E. Teso,Fraile, A. Garcia,Barcina, J. Osio,Hanack, M.,Subramanian, L.R.
, p. 1503 - 1506 (1989)
The solvolysis of 2,2,3- and 2,3,3-trimethyl substituted 1-norbornyl triflates 1 and 6 in 60percent aqueous ethanol at 60 deg C proceeds via novel ?-bridged carbocations affording products mainly from hitherto unknown Wagner-Meerwein rearrangement and fragmentation reactions, respectively.
