Tetrahedron Letters p. 1503 - 1506 (1989)
Update date:2022-08-04
Topics:
Martinez, A. Garcia
Vilar, E. Teso
Fraile, A. Garcia
Barcina, J. Osio
Hanack, M.
Subramanian, L.R.
The solvolysis of 2,2,3- and 2,3,3-trimethyl substituted 1-norbornyl triflates 1 and 6 in 60percent aqueous ethanol at 60 deg C proceeds via novel ?-bridged carbocations affording products mainly from hitherto unknown Wagner-Meerwein rearrangement and fragmentation reactions, respectively.
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