686294-49-5

Basic information

• Product Name: 1-Propanone, 1-(1-methylcyclopropyl)-3-[(4S)-4-(1-methylethenyl)-1-cyclohexen-1-yl]-
• CAS NO: 686294-49-5
• Molecular Formula: C16H24O
• Molecular Weight: 232.366
• Mol File: 686294-49-5.mol

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 1-(1-methylcyclopropyl)-3-[(4S)-4-(1-methylethenyl)-1-cyclohexen-1-yl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 1-(1-methylcyclopropyl)-3-[(4S)-4-(1-methylethenyl)-1-cyclohexen-1-yl]-(686294-49-5)
• EPA Substance Registry System: 1-Propanone, 1-(1-methylcyclopropyl)-3-[(4S)-4-(1-methylethenyl)-1-cyclohexen-1-yl]-(686294-49-5)

Safety Data

• Hazardous Substances Data: 686294-49-5(Hazardous Substances Data)

Upstream product

• 686294-48-4 ethyl 2-[(4-isopropenyl-1-cyclohexenyl)methyl]-3-(1-methylcyclopropyl)-3-oxopropanoate 
• 32249-37-9 Ethyl 3-(1-methylcycloprop-1-yl)-3-oxopropionate 
• 83059-12-5 (S)-1-(bromomethyl)-4-(prop-1-en-2-yl)cyclohex-1-ene 

Downstream Products

• 686294-51-9 (E)-1-bromo-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexene 
• 502851-07-2 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-3-methyl-1-cyclohexenyl trimethylsilyl ether 
• 502851-06-1 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-2-cyclohexen-1-one 
• 502851-05-0 (E)-1-iodo-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexene 
• 686294-50-8 3-(4-isopropenyl-1-cyclohexenyl)-1-(1-methylcyclopropyl)-1-propanol 

Relevant articles and documents

Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers

Photoinduced electron transfer was used to activate silyl enol ethers. The generated radical cations of specifically designed precursors undergo ring closure reactions to yield novel steroid compounds. These domino reactions proceed with high stereoselectivity. The synthesis of the complex silyl enol ethers, the stereo-selective domino cyclization process and the assignment of stereochemistry of the novel steroid compounds is presented.