502851-07-2

Basic information

• Product Name: 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-3-methyl-1-cyclohexenyl trimethylsilyl ether
• Synonyms: 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-3-methyl-1-cyclohexenyl trimethylsilyl ether
• CAS NO: 502851-07-2
• Molecular Weight: 400.72
• Mol File: 502851-07-2.mol

Chemical Properties

• CAS DataBase Reference: 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-3-methyl-1-cyclohexenyl trimethylsilyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-3-methyl-1-cyclohexenyl trimethylsilyl ether(502851-07-2)
• EPA Substance Registry System: 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-3-methyl-1-cyclohexenyl trimethylsilyl ether(502851-07-2)

Safety Data

• Hazardous Substances Data: 502851-07-2(Hazardous Substances Data)

Upstream product

• 686294-51-9 (E)-1-bromo-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexene 
• 686294-50-8 3-(4-isopropenyl-1-cyclohexenyl)-1-(1-methylcyclopropyl)-1-propanol 
• 686294-49-5 3-(4-isopropenyl-1-cyclohexenyl)-1-(1-methylcyclopropyl)-1-propanone 
• 502851-05-0 (E)-1-iodo-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexene 
• 83059-12-5 (S)-1-(bromomethyl)-4-(prop-1-en-2-yl)cyclohex-1-ene 
• 75-77-4 chloro-trimethyl-silane 
• 917-54-4 methyllithium 
• 502851-06-1 3-[(E)-6-(4-isopropenyl-1-cyclohexenyl)-3-methyl-3-hexenyl]-2-cyclohexen-1-one 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

Synthesis of novel steroid backbones via photoinduced electron transfer initiated domino cyclizations of silyl enol ethers

Photoinduced electron transfer was used to activate silyl enol ethers. The generated radical cations of specifically designed precursors undergo ring closure reactions to yield novel steroid compounds. These domino reactions proceed with high stereoselectivity. The synthesis of the complex silyl enol ethers, the stereo-selective domino cyclization process and the assignment of stereochemistry of the novel steroid compounds is presented.

Synthesis and PET oxidative cyclization of silyl enol ethers: Build-up of quasi-steroidal carbocycles

PET oxidative cyclization of silyl enol ethers carrying suitable side chains with olefinic double bonds results in the stereoselective formation of carbocycles. Two model compounds for investigating the influence of silyl enol ether ring size are synthesi