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Jacobine is a pyrrolizidine alkaloid belonging to the group of bases found in Senecio cineraria D.C., S. crucifolia, and S. Jacobea. It is a laevorotatory base with specific optical rotation values and forms crystalline salts and derivatives. The alkaloid contains two active hydrogens and upon alkaline hydrolysis, it yields retronecine and jaconecic acid.

6870-67-3

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6870-67-3 Usage

Uses

Used in Pest Control:
Jacobine is used as an herbivore insect deterrent in the protection of vegetation. It is extracted from the Crassocephalum plant of West Africa and helps in keeping insects at bay, thus preserving the plants.

References

Manske., Can. J. Res., 5,651 (1931)Hosking, Brandt., New Zealand J. Sci. Tech., 14,638 (1936)Blackie.,Pharrn. J., 138,102 (1937)Barger, Blackie., J. Chern. Soc., 584 (1937)Bradbury, Willis., Austral. J. Chern., 9,258 (1956)Geissman., ibid, 12,247 (1959)Bradbury, Masamune., J. Arner. Chern. Soc., 81,5201 (1959)Masamune., ibid, 82, 5253 (1960)Freidrichsons, Mathieson, Sutor., Tetrahedron Lett., 35 (1960)

Check Digit Verification of cas no

The CAS Registry Mumber 6870-67-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,8,7 and 0 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 6870-67:
(6*6)+(5*8)+(4*7)+(3*0)+(2*6)+(1*7)=123
123 % 10 = 3
So 6870-67-3 is a valid CAS Registry Number.
InChI:InChI=1/C18H25NO6/c1-10-8-18(11(2)25-18)16(21)24-13-5-7-19-6-4-12(14(13)19)9-23-15(20)17(10,3)22/h4,10-11,13-14,22H,5-9H2,1-3H3/t10-,11-,13-,14-,17-,18+/m1/s1

6870-67-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Jacobine

1.2 Other means of identification

Product number -
Other names (15R,20S)-15,20-Dihydro-15,20-epoxy-12-hydroxysenecionan-11,16-dione

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6870-67-3 SDS

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