68724-63-0Relevant academic research and scientific papers
Generation of Allylic and Related Organozirconiums Through A Highly Effective Zirconium-β-Alkoxide Elimination Reaction
Ito, Hisanaka,Nakamura, Takanori,Taguchi, Takeo,Hanzawa, Yuji
, p. 4507 - 4518 (2007/10/02)
Reactions and characterization of allylic and related zirconium reaegnts (allenic and γ-alkoxyallylic zirconiums) generated by treatment of allylic and/or propargylic ethers with a zirconocene-butene complex ("Cp2Zr") are described.
REGIOREVERSED REACTIONS OF TRIMETHYLSILYL OR PHENYLSELENYL ALLYLIC CARBANION WITH CARBONYL COMPOUNDS VIA ALLYLIC ALUMINUM "ATE" COMPLEXES
Yamamoto, Yoshinori,Saito, Yoshikazu,Maruyama, Kazuhiro
, p. 4597 - 4600 (2007/10/02)
Triethylaluminum "ate" complexes of trimethylsilyl and phenylselenyl allylic carbanion react with carbonyl compounds at the α-position either exclusively or predominantly.
A STEREOCONTROLLED SYNTHESIS OF Z AND E TERMINAL DIENES FROM PINACOL E-1-TRIMETHYLSILYL-1-PROPENE-3-BORONATE
Tsai, David Jieh Shyh,Matteson, Donald S.
, p. 2751 - 2752 (2007/10/02)
Pinacol E-1-trimethylsilyl-1-propene-3-boronate reacts with aldehydes to form (+)-(R*, S*)-3-trimethylsilyl-4-hydroxy-1-alkenes, which can be deoxysilylated stereoselectively to either 98percent Z or 99percent E 1,3-dienes, including the separate components of the red bollworm moth pheromone.
