68763-06-4

Basic information

• Product Name: (E,E,E)-2,4,6-tristyrylpyrimidine
• Synonyms: (E,E,E)-2,4,6-tristyrylpyrimidine
• CAS NO: 68763-06-4
• Molecular Weight: 386.496
• Mol File: 68763-06-4.mol

Chemical Properties

• CAS DataBase Reference: (E,E,E)-2,4,6-tristyrylpyrimidine(CAS DataBase Reference)
• NIST Chemistry Reference: (E,E,E)-2,4,6-tristyrylpyrimidine(68763-06-4)
• EPA Substance Registry System: (E,E,E)-2,4,6-tristyrylpyrimidine(68763-06-4)

Safety Data

• Hazardous Substances Data: 68763-06-4(Hazardous Substances Data)

Upstream product

• 56536-48-2 2,4,6-trimethylpyrimidine 1-oxide 
• 100-52-7 benzaldehyde 
• 3764-01-0 2,4,6-trichloropyrimidine 
• 201852-49-5 potassium (E)-trifluoro(styryl)borate 
• 4472-44-0 2-chloro-4,6-dimethylpyrimidine 
• 536-74-3 phenylacetylene 
• 77204-31-0 4,6-dimethyl-2-trans-styrylpyrimidine 
• 123-54-6 acetylacetone 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 22114-27-8 2,4,6-trimethylpyrimidine 

Relevant articles and documents

Suzuki-Miyaura cross-coupling reactions of potassium alkenyltrifluoroborates

We have previously reported that the palladium-catalyzed cross-coupling reaction of air-stable potassium alkenyltrifluoroborates with aryl halides and triflates proceeds readily with good yields. Recent progress in outlining the scope and limitations of s

2,4-Distyryl- and 2,4,6-Tristyrylpyrimidines: Synthesis and Photophysical Properties

The synthesis of a series of 20 new 2,4,6-tristyrylpyrimidines and three new 2,4-distyrylpyrimidines by means of combination of Knoevenagel condensation and Suzuki-Miyaura cross-coupling reaction is reported. This methodology enables us to obtain chromophores with identical or different substituent on each arm. The photophysical properties of the compounds are described. Optical properties and time-dependent density functional theory calculations indicate that photophysical properties of target compounds are mainly affected by the nature of the electron-donating group in C4/C6 positions, except when the C2 substituent is a significantly stronger electron-donating group. However, the C2 substituent has a strong influence on emission quantum yield: addition of a strong electron-donating group tends to decrease the fluorescence quantum yield, whereas a moderate electron-withdrawing group results in a significant increase of fluorescence quantum yield.

Studies on Pyrimidine Derivatives. XVIII. Reaction of Active Methyl Groups on Pyrimidine N-Oxides

Knoevenagel-type condensation and the Mannich reaction were investigated with various pyridine N-oxides having an active methyl group.For example, 6-methyl-4-phenylpyrimidine 1-oxide (Va) readily reacted with benzaldehyde in an aqueous ethanolic solution