688047-86-1Relevant articles and documents
Using monovalent phosphorus compounds to form P-C bonds
Ng, Yong Xiang,Mathey, Francois
, p. 14140 - 14142 (2013)
User friendly P-C: Electrophilic terminal phosphinidene complexes [RP-W(CO)5] react with Ar-B(OH)2 to give the corresponding secondary phosphine complexes [{R(Ar)PH}W(CO)5]. This method enables the formation of P-C bonds through the combination of a wide array of heterocyclic and aryl boronic acids with various electrophilic phosphinidene complexes. The final products incorporate a P-H bond that can be used for further transformations. Copyright