688049-03-8

Basic information

• Product Name: (1R,3S,4S)-3-[(R)-1-((R)-Hydroxy-phenyl-methyl)-2-oxo-propylselanyl]-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one
• CAS NO: 688049-03-8
• Molecular Weight: 393.385
• Mol File: 688049-03-8.mol

Chemical Properties

• CAS DataBase Reference: (1R,3S,4S)-3-[(R)-1-((R)-Hydroxy-phenyl-methyl)-2-oxo-propylselanyl]-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,3S,4S)-3-[(R)-1-((R)-Hydroxy-phenyl-methyl)-2-oxo-propylselanyl]-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one(688049-03-8)
• EPA Substance Registry System: (1R,3S,4S)-3-[(R)-1-((R)-Hydroxy-phenyl-methyl)-2-oxo-propylselanyl]-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one(688049-03-8)

Safety Data

• Hazardous Substances Data: 688049-03-8(Hazardous Substances Data)

Upstream product

• 155631-33-7 C₁₀H₁₅ClOSe 
• 100-52-7 benzaldehyde 
• 688048-70-6 (1R,3S,4S)-1,7,7-Trimethyl-3-(2-oxo-propylselanyl)-bicyclo[2.2.1]heptan-2-one 

Downstream Products

• 5381-93-1 (4S)-4-hydroxy-4-phenylbutan-2-one 

Relevant articles and documents

Asymmetric aldol reactions from titanium enolates of α-seleno ketones and esters

Asymmetric aldol condensations using titanium enolates of (R)-camphorselenoacetone and of methyl (R)-camphorselenoacetate are reported. The reactions with aromatic, α,β-unsaturated or aliphatic aldehydes proceed with good chemical yields giving a mixture of the syn and anti aldols. These diastereoisomers were easily separated by column chromatography. The two syn diastereoisomers were obtained in enantiomerically pure form.