68857-83-0Relevant academic research and scientific papers
Solvolysis of 1-alkyl-1-chloro-1-(4-methyl)phenylmethanes. Nucleophilic solvent intervention and extended YBnCl scale
Liu, Kwang-Ting,Chang, Lih-Wie,Yu, Der-Gann,Chen, Pang-Shao,Fan, Ju-Ta
, p. 879 - 884 (2007/10/03)
The solvolysis of 1-alkyl-1-chloro-1-(4-methyl)phenylmethanes (4a-d) in aqueous acetone, aqueous ethanol, aqueous methanol and ethanol-trifluoroethanol was studied. Grunwald-Winstein-type correlation analysis using the YBnCl scale suggests significant nucleophilic solvent intervention in the case of 1-chloro-1-(4-methyl)phenylethane (4a). Increasing bulkiness of the 1-alkyl substituent from methyl (4a) to ethyl (4b), to isopropyl (4c) and to tert-butyl (4d) resulted in a gradual change to limiting SN1 mechanisms. The observed excellent linear correlations with YBnCl and the good solubility in high-water-containing binary solvents made 4d a suitable reference standard for deriving more YBnCl values. A positive azide salt effect was realized in the solvolysis of 4a but not 4d. A small decrease in the β-deuterium kinetic isotope effect from 4a to 1-chloro-1-(4-methoxyphenyl)propane (5) suggested the presence of additional stabilization of the benzylic cationic transition state. However, no relationship between k(CH3)/k(CD3) and the solvent effect was found. The superiority of employing the YBnCl scale over the combination of YCl and I scales in the mehanistic study was observed.
Formate ester indane compounds
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, (2008/06/13)
The present invention relates to novel formate ester indane compounds having fragrant musk-like aroma.
Novel acyl-polyalkylindan compounds and the use thereof as a base for perfume, as well as perfume compositions
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, (2008/06/13)
Novel acyl-polyalkyl indan compounds and the use thereof as a base for perfume, as well as perfume compositions, perfumed materials and perfumed articles.
