68893-64-1Relevant academic research and scientific papers
Neighboring-group participation in the hydrolysis of coordinated nitriles
Balahura, Robert J.,Purcell
, p. 4159 - 4163 (1981)
The hydrolysis reaction (Chemical Equation Presented) has been studied. For R = CN, kh = 1050 ± 60 M-1 s-1, ΔH? = 13.6 ± 0.5 kcal mol-1, ΔS? = 1.0 ± 2 eu at 25°C, and I = 1.0 M (LiClO4). For R = CONH
