Neighboring-group participation in the hydrolysis of coordinated nitriles

DOI: 10.1021/ic50226a026

Source and publish data:

Inorganic Chemistry p. 4159 - 4163 (1981)

Update date:2022-09-26

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Authors:

Balahura, Robert J.

Purcell Purcell

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Article abstract of DOI:10.1021/ic50226a026

The hydrolysis reaction (Chemical Equation Presented) has been studied. For R = CN, k_h = 1050 ± 60 M^-1 s^-1, ΔH? = 13.6 ± 0.5 kcal mol^-1, ΔS? = 1.0 ± 2 eu at 25°C, and I = 1.0 M (LiClO₄). For R = CONH<

Full text of DOI:10.1021/ic50226a026

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