69022-01-1

Basic information

• Product Name: trans-[PtCl₂(o-tolylmethylsulfide)2]
• CAS NO: 69022-01-1
• Molecular Weight: 542.453
• Mol File: 69022-01-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[PtCl₂(o-tolylmethylsulfide)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[PtCl₂(o-tolylmethylsulfide)2](69022-01-1)
• EPA Substance Registry System: trans-[PtCl₂(o-tolylmethylsulfide)2](69022-01-1)

Safety Data

• Hazardous Substances Data: 69022-01-1(Hazardous Substances Data)

Upstream product

• 13965-91-8 tetrachloroplatinum(II) 
• 14092-00-3 methyl o-tolyl sulfide 
• 14873-63-3 bis(benzonitrile)dichloroplatinum(II) 

Downstream Products

• 844467-15-8 cis-[Pt(OAc)2(MeS-o-C₆H₄Me)2] 

Relevant articles and documents

Chloro and acetato complexes of platinum(II) with functionalized thioethers

The chloro complexes [PtCl2(RSR′)2] (1-10) (RSR′ = MeSCH2C(O)OMe, 1; MeSCH2C(O)OEt, 2; MeSCH2C(O)Omenthyl(-), 3; MeSCH2CH2C(O)OMe, 4;, 5; EtSCH2C(O)Me, 6; MeSCH(Me)C(O)Me, 7; MeSPh, 8; MeS-o-C 6H4Me, 9; and MeS-o-C6H4Et, 10) are obtained in high yield (63-90%) by reaction of [PtCl2(PhCN) 2] with the proper thioether in 1/2 molar ratio, in anhydrous chloroform, at reflux under argon for ca. 10 h. The X-ray crystal structure of [PtCl2(MeS-o-C6H4Me)2] (9) shows an almost regular trans square planar geometry (triclinic, space group P1?, a 6.806(1), b 7.789(2), c 10.085(3) ?, α 101.80(2)°, β 69.55(2)°, γ 115.27(2)°, R(Fo) 0.023, R w(Fo2)0.065). The dichloro complexes react with silver acetate in a complex manner, which depends on the nature of the thioether, and only with RSR′ = MeSPh the simple diacetato complex [Pt(OAc)2(RSR′)2] is obtained as the major product.