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14092-00-3

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14092-00-3 Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 111, p. 654, 1989 DOI: 10.1021/ja00184a038

Check Digit Verification of cas no

The CAS Registry Mumber 14092-00-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,0,9 and 2 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 14092-00:
(7*1)+(6*4)+(5*0)+(4*9)+(3*2)+(2*0)+(1*0)=73
73 % 10 = 3
So 14092-00-3 is a valid CAS Registry Number.
InChI:InChI=1/C8H10S/c1-7-4-2-3-5-8(7)6-9/h2-5,9H,6H2,1H3

14092-00-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-METHYLBENZYL MERCAPTAN, 97

1.2 Other means of identification

Product number -
Other names methyl(o-tolyl)sulfane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14092-00-3 SDS

14092-00-3Relevant articles and documents

-

Figuly,G.D.,Loop,C.K.,Martin,J.C.

, p. 654 (1989)

-

The Aryl Sulfide Synthesis via Sulfide Transfer

Huang, Hui,Li, Xiang,Liang, Xinyu,Lin, Qijie,Ma, Bowei,Pei, Shurui,Shi, Qinqin,Wang, Song,Wang, Zhi-Xiang,Wen, Kaikai,Zhang, Bei-Bei,Zhang, Meng

supporting information, (2022/05/14)

Aryl sulfides are in great demands in drugs and materials sciences. To avoid using nucleophilic and noxious thiols, many efforts have been focused on exploring novel sulfide resources. Herein, a reductive Pd-catalyzed, Ni-mediated method to synthesize aryl sulfides via a sulfide transfer reaction is developed. The utility and scope of this reaction is exemplified by various aryl electrophiles and aryl sulfides. Mechanistic studies reveal two competing catalytic cycles of sulfide transfer and aryl transfer in this reaction, where the former one is favored over the later one because of the large energy barrier difference during the transmetalation. Moreover, two important chemicals are late-stage functionalized by this method, exhibiting the potential applications in drugs and materials science.

Synthesis of Aryl Methyl Sulfides from Arysulfonyl Chlorides with Dimethyl Carbonate as the Solvent and C1 Source

Miao, Ren-Guan,Qi, Xinxin,Wu, Xiao-Feng

supporting information, p. 5219 - 5221 (2021/10/19)

A new procedure for the synthesis of aryl methyl sulfides from dimethyl carbonate (DMC) and arylsulfonyl chlorides has been achieved. In this strategy, DMC plays a dual role as both, C1 building block and green solvent. Arylsulfonyl chlorides served as the sulfur precursors, and a variety of aryl methyl sulfides were obtained in moderate to excellent yields with good functional group tolerance. Additionally, alkylsulfonyl chloride and dibenzyl carbonate are proven to be suitable substrates as well.

Iridium-Catalyzed ortho-C-H Borylation of Thioanisole Derivatives Using Bipyridine-Type Ligand

Kuninobu, Yoichiro,Naito, Morio,Torigoe, Takeru,Yamanaka, Masahiro,Zeng, Jialin

supporting information, (2020/05/08)

A simple iridium catalytic system was developed that allows for a variety of 2-borylthioanisoles to be easily synthesized via ortho-selective C-H borylation of thioanisole derivatives. Once introduced, boryl and methylthio groups were converted by palladium-catalyzed transformations. Density functional theory calculations revealed that weak interactions, such as hydrogen bonding between the C-H bond of the SCH3 group and the oxygen atom of the boryl ligand, control the ortho-selectivity.

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