69032-16-2

Basic information

• Product Name: Carbonisocyanatidic acid, phenylmethyl ester
• CAS NO: 69032-16-2
• Molecular Formula: C9H7NO3
• Molecular Weight: 177.159
• Mol File: 69032-16-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Carbonisocyanatidic acid, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonisocyanatidic acid, phenylmethyl ester(69032-16-2)
• EPA Substance Registry System: Carbonisocyanatidic acid, phenylmethyl ester(69032-16-2)

Safety Data

• Hazardous Substances Data: 69032-16-2(Hazardous Substances Data)

Upstream product

• 79-37-8 oxalyl dichloride 
• 621-84-1 O-benzyl carbamate 

Downstream Products

• 120542-11-2 N-Benzyloxycarbonyl-glycin-(4-nitro-benzylester) 
• 120542-16-7 benzyl 2,2,2-trichloroethylimidodicarbonate 
• 120542-12-3 C₁₈H₁₉NO₄ 
• 1449435-10-2 (R)-benzyl 2-oxo-4-(2-oxo-2-phenylethyl)oxazolidine-3-carboxylate 
• 1323371-12-5 C₂₃H₂₄N₄O₆ 
• 1067181-10-5 N-[(2,4,6-trimethylphenyl)sulfonyl]-N'-benzyloxycarbonyl-(S)-methylisothiourea 
• 32339-07-4 4-nitrobenzyl carbamate 
• 139928-85-1 C₂₁H₂₂ClNO₆ 
• 139928-82-8 C₁₈H₂₂Cl₃NO₆ 
• 139928-84-0 C₂₁H₂₂ClNO₆ 
• 139928-86-2 C₂₀H₂₂N₂O₆ 
• 139928-88-4 C₂₁H₂₃NO₅S 
• 151416-18-1 5-[[[[(phenylmethoxy)carbonyl]amino]carbonyl]amino]-1-(β-D-ribofuranosyl)-1H-imidazole-4-carboxylic acid diphenylmethyl ester 
• 155301-76-1 C₁₈H₂₀N₄O₉ 

Relevant articles and documents

Procedure-controlled enantioselectivity switch in organocatalytic 2-oxazolidinone synthesis

In a novel organocatalytic formal [3 + 2] cycloaddition to afford chiral 2-oxazolidinones, an enantioselectivity switch could be induced by changing the manner of addition of the reactants, even when the reaction components (cinchona-alkaloid-derived aminothiourea catalyst, substrates, and solvent) were the same.

Convenient Preparation of Alkyl Benzyl Imidodicarbonates, Useful Reagents for the Direct Synthesis of Protected Amines

New mixed alkyl benzyl imidodicarbonates were prepared by reaction of benzyloxycarbonyl isocyanate with appropriate alcohols.This simple procedure also furnished alternative, more convenient routes to dibenzyl and benzyl 9-fluorenylmethyl imidodicarbonates.The substances are of interest as potential Gabriel reagents.Completely selective removal of one of the alkoxycarbonyl groups from the N-atom of the imidodicarbonates was demonstrated in several instances, giving benzyl carbamate or the alternative carbamate.