69047-43-4

Basic information

• Product Name: N-(2-methylphenyl)-2-(2-thienyl)acetamide
• Synonyms: N-(2-methylphenyl)-2-(2-thienyl)acetamide
• CAS NO: 69047-43-4
• Molecular Formula: C₁₃H₁₃NOS
• Molecular Weight: 231.31342
• Mol File: 69047-43-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-(2-methylphenyl)-2-(2-thienyl)acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-methylphenyl)-2-(2-thienyl)acetamide(69047-43-4)
• EPA Substance Registry System: N-(2-methylphenyl)-2-(2-thienyl)acetamide(69047-43-4)

Safety Data

• Hazardous Substances Data: 69047-43-4(Hazardous Substances Data)

Upstream product

• 4461-29-4 2-(thiophen-2-yl)acetamide 
• 95-49-8 2-methylchlorobenzene 
• 39098-97-0 2-thienylacetic acid chloride 
• 95-53-4 o-toluidine 
• 1918-77-0 Thiophene-2-acetic acid 

Relevant articles and documents

Late-Stage Diversification of Biarylphosphines through Rhodium(I)-Catalyzed C-H Bond Alkenylation with Internal Alkynes

We report herein P(III)-directed C-H bond alkenylation of (dialkyl)- and (diaryl)biarylphosphines using internal alkynes. Chloride-free [Rh(OAc)(COD)]2 acts as a better catalyst than commercially available [RhCl(COD)]2. Conditions were developed to control the mono- and difunctionalization depending on the alkyne stoichiometry. One of these novel bisalkenylated (dialkyl)biarylphosphines was employed for the preparation of a palladium(II) complex, and some of these functionalized ligands outperformed their corresponding unfunctionalized phosphines in Pd-catalyzed amidation with sterically hindered aryl chlorides.

A New Reagent for Activating Carboxyl Groups; Preparation and Reactions of N,N-Bisphosphorodiamidic Chloride

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