69087-52-1Relevant articles and documents
Asymmetric Induction by a Nitrogen14N/15N Isotopomer in Conjunction with Asymmetric Autocatalysis
Matsumoto, Arimasa,Ozaki, Hanae,Harada, Shunya,Tada, Kyohei,Ayugase, Tomohiro,Ozawa, Hitomi,Kawasaki, Tsuneomi,Soai, Kenso
, p. 15246 - 15249 (2016)
Chirality arising from isotope substitution, especially with atoms heavier than the hydrogen isotopes, is usually not considered a source of chirality in a chemical reaction. An N2,N2,N3,N3-tetramethyl-2,3-butan
CYCLISATION PROCESS OF FORMING A MULTIPLE RING COMPOUND
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Page/Page column 4; 45; 17, (2010/11/28)
The present invention relates to a cyclisation process of forming a multiple ring compound from an isoprenoid compound. The cyclisation process involves reacting the isoprenoid compound with an acetal initiator under conditions sufficient to form the multiple ring compound. The isoprenoid compound is contacted with an initiator an optionally with a catalyst. Cyclisation occurs by reaction of the initiator with the isoprenoid compound. Cyclic aceta compounds wherein the acetal forms part of 6-membered unsaturated ring are also defined.