69093-06-7Relevant academic research and scientific papers
Decomposition of bis( silyldiazomethyl) polysilanes: formation of polysilabicyclo(l.m.n)alkane derivatives
Ando, Wataru,Sugiyama, Mitsuru,Suzuki, Tomohisa,Kato, Chikako,Arakawa, Yusuke,Kabe, Yoshio
, p. 99 - 112 (2007/10/02)
The photolysis of bis(trimethylsilyldiazomethyl)disilane (4a) in tert-butyl alcohol provided the tert-butyl alcohol adducts S, 6, 7, 8 and 9.The structures of these products revealed the stepwise formation of asymmetric silenes as intermediates.Gas-phase
PHOTOLYSIS AND THERMOLYSIS OF 1,2,3-TRISILACYCLOPENTENE. REGIOSPECIFIC AND NON-REGIOSPECIFIC SILYLENE EXTRUSION.
Nakadaira, Yasuhiro,Sato, Ryuji,Kida, Nobutsugu,Sakurai, Hideki
, p. 393 - 396 (2007/10/02)
1,2,3-Trisilacyclopent-4-ene generates silylene to give 1,2-disilacyclobut-3-ene on both photolysis and thermolysis.The silylene arises from either the central or the terminal silicon atom of the ring depending on the nature of substituents on the central
