79628-15-2Relevant articles and documents
Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation
Capaldo, Luca,Ravelli, Davide
, p. 2243 - 2247 (2021/04/05)
A versatile approach for the alkynylation of a variety of aliphatic hydrogen donors, including alkanes, is reported. We used tetrabutylammonium decatungstate as photocatalyst to generate organoradicals from C-H/Si-H bonds via hydrogen atom transfer. The l
Tuning the Selectivity of AuPd Nanoalloys towards Selective Dehydrogenative Alkyne Silylation
Wissing, Maren,Studer, Armido
supporting information, p. 5870 - 5874 (2019/03/21)
The cross-dehydrogenative coupling of terminal alkynes and hydrosilanes catalyzed by AuPd nanoalloys is described. Metal nanoparticles are readily prepared in 15 minutes from commercially available and cheap starting materials by using a photochemical app
Ru-Catalyzed Migratory Geminal Semihydrogenation of Internal Alkynes to Terminal Olefins
Song, Lijuan,Feng, Qiang,Wang, Yong,Ding, Shengtao,Wu, Yun-Dong,Zhang, Xinhao,Chung, Lung Wa,Sun, Jianwei
supporting information, p. 17441 - 17451 (2019/11/03)
Semihydrogenation of alkynes to alkenes represents a fundamentally useful transformation. In addition to the well-known cis- and trans-semihydrogenation, herein a geminal semihydrogenation of internal alkynes featuring 1,2-migration is described, which pr