79628-15-2

Upstream product

• 69093-06-7 1,1,2,2-tetramethyl-3,4-diphenyl-1,2-disilacyclobut-3-ene 
• 91708-97-3 1,1,3,3-Tetramethyl-2,2,4,5-tetraphenyl-2,3-dihydro-1H-[1,2,3]trisilole 
• 33668-60-9 iodo(dimethyl)(phenyl)silane 
• 536-74-3 phenylacetylene 
• 768-33-2 phenyldimethylsilyl chloride 
• 13146-23-1 copper(I) phenylacetylenide 
• 766-77-8 Dimethylphenylsilane 
• 1833-51-8 chloromethyldimethylphenylsilane 
• 91708-98-4 2-Ethyl-1,1,2,3,3-pentamethyl-4,5-diphenyl-2,3-dihydro-1H-[1,2,3]trisilole 
• 69093-08-9 1,1,2,2,3,3-hexamethyl-4,5-diphenyl-2,3-dihydro-1H-1,2,3-trisilole 
• 31731-63-2 2,2,5,5-tetramethyl-3,4-diphenyl-2,5-dihydro-1,2,5-oxadisilole 
• 28995-82-6 ((Z)-1-Iodo-2-methanesulfonyl-vinyl)-benzene 
• 24378-05-0 methyl phenylethynyl sulfone 
• 591-50-4 iodobenzene 

Downstream Products

• 1694-19-5 E-1-(phenyl)-2-(4'-methoxyphenyl)ethene 
• 841-18-9 (E)-1-(4-acetamidophenyl)-2-phenylethene 
• 3783-65-1 (E)-2-(2-phenylethenyl)thiophene 
• 141858-80-2 (E)-1-<2-(acetoxymethyl)phenyl>-2-phenylethene 
• 1438769-20-0 (E)-1-iodo-1-dimethyl(phenyl)silyl-2-phenylethene 
• 1438770-06-9 1-dimethyl(phenyl)silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene 
• 63935-90-0 1-(dimethyl(phenyl)silyl)-1-phenylethene 
• 64788-84-7 β-(Z)-2-dimethylphenylsilylstyrene 
• 64788-85-8 dimethyl-phenyl-((E)-styryl)-silane 
• 109463-33-4 5-(1,1,1,3,3,3-Hexamethyl-disilazan-2-yl)-3-phenyl-4-trimethylsilanyl-1H-pyrrole-2-carbonitrile 
• 772-62-3 3,3,3-trifluoro-1-phenylpropyne 

Relevant academic research and scientific papers

Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation

A versatile approach for the alkynylation of a variety of aliphatic hydrogen donors, including alkanes, is reported. We used tetrabutylammonium decatungstate as photocatalyst to generate organoradicals from C-H/Si-H bonds via hydrogen atom transfer. The l

Catalytic Decarboxylation of Silyl Alkynoates to Alkynylsilanes

Herein, we describe a decarboxylative approach to the preparation of alkynylsilanes. Treatment of a silyl alkynoate in N,N-dimethylformamide (DMF) at 80 °C in the presence of catalytic amounts of CuCl and PCy3 produced the corresponding alkynylsilane in excellent yield. The copper-catalyzed decarboxylation proceeded smoothly with low catalyst loadings (0.5 mol % of CuCl and 1.0 mol % of PCy3) under mild reaction conditions and is easily scalable to gram quantities.

Et2Zn-mediated stoichiometric C(sp)-H silylation of 1-alkynes and chlorosilanes

A first example of an Et2Zn mediated silylation of 1-aklynes is reported. A series of functional groups are tolerated in this reaction. Mechanistic studies support Zn alkynilides as intermediates in the reaction. This reaction protocol provides a practical method for the preparation of alkynylsilanes and expands the application of organometallic zinc in organic synthesis.

Ru-Catalyzed Migratory Geminal Semihydrogenation of Internal Alkynes to Terminal Olefins

Semihydrogenation of alkynes to alkenes represents a fundamentally useful transformation. In addition to the well-known cis- and trans-semihydrogenation, herein a geminal semihydrogenation of internal alkynes featuring 1,2-migration is described, which pr

Tuning the Selectivity of AuPd Nanoalloys towards Selective Dehydrogenative Alkyne Silylation

The cross-dehydrogenative coupling of terminal alkynes and hydrosilanes catalyzed by AuPd nanoalloys is described. Metal nanoparticles are readily prepared in 15 minutes from commercially available and cheap starting materials by using a photochemical app

Role of C, S, Se and P donor ligands in copper(i) mediated C-N and C-Si bond formation reactions

The first comparative study of C, S, Se and P donor ligands-supported copper(i) complexes for C-N and C-Si bond formation reactions are described. The syntheses and characterization of eight mononuclear copper(i) chalcogenone complexes, two polynuclear co

Alkali metal-hydroxide-catalyzed C(sp)-H Bond silylation

Disclosed is a mild, scalable, and chemoselective catalytic cross-dehydrogenative C-H bond functionalization protocol for the construction of C(sp)-Si bonds in a single step. The scope of the alkyne and hydrosilane partners is substantial, providing an entry point into various organosilane building blocks and additionally enabling the discovery of a number of novel synthetic strategies. Remarkably, the optimal catalysts are NaOH and KOH.

BASE-CATALYZED SILYLATION OF TERMINAL ALKYNE C-H BONDS

The present invention is directed to a mild, efficient, and general direct C(sp)-H bond silylation. Various embodiments includes methods, each method comprising or consisting essentially of contacting at least one organic substrate comprising a terminal a

Synthesis and reactions of donor cyclopropanes: efficient routes to cis- and trans-tetrahydrofurans

Abstract A detailed study on the synthesis and reactions of silylmethylcyclopropanes is reported. In their simplest form, these donor-only cyclopropanes undergo Lewis acid promoted reaction to give either cis- or trans-tetrahydrofurans, with the selectivity being reaction condition-dependant. The adducts themselves are demonstrated to be an important scaffold for structural diversification. The combination of a silyl-donor group in a donor-acceptor cyclopropane with novel acceptor groups is also discussed.

Iridium-promoted conversion of chlorosilanes to alkynyl derivatives in a one-pot reaction sequence

By making use of the catalytic potential of the iridium system [{Ir(μ-Cl)(CO)2}2]/NEt(i-Pr)2 in the synthesis of silyl-functionalized alkynes via silylative coupling of terminal alkynes/diynes with iodosilanes, we propose