690949-10-1Relevant academic research and scientific papers
Investigations into the manzamine alkaloid biosynthetic hypothesis
Baldwin, Jack E.,Claridge, Timothy D. W.,Culshaw, Andrew J.,Heupel, Florian A.,Lee, Victor,Spring, David R.,Whitehead, Roger C.,Boughtflower, Robert J.,Mutton, Ian M.,Upton, Richard J.
, p. 2661 - 2663 (2007/10/03)
The biomimetic synthesis of a pentacyclic alkaloid (keramaphidin B, 1), an intermediate in the biogenetic pathway to the manzamine alkaloids, has been achieved. Compound 1 was formed by an intramolecular Diels-Alder reaction of macrocycle 2 in buffer foll
