691-05-4Relevant academic research and scientific papers
Simultaneous scission of C-S and S-S bonds of bis(trifluoromethyl)trisulfide by Grignard reagents
Munavalli, Shekar,Rossman, David I.,Rohrbaugh, Dennis K.,Ferguson, C. Parker,Szafraniec, Leonard J.
, p. 91 - 99 (2007/10/02)
Trifluoromethyl mono-, di- and tri-sulfides, and alkyl sulfides and disulfides, as well as dimerized products, are formed as a result of the simultaneous cleavage of the C-S and S-S bonds of bis(trifluoromethyl)trisulfide by Grignard reagents at -78 deg C.The formation of various products has been rationalized on the basis of the involvement of free radicals.
Chemistry of trifluoromethylsulfinyl fluoride. Trifluoromethylsulfinamides and trifluoromethylsulfinate esters
Sauer, Dennis T.,Shreeve, Jean'ne M.
, p. 358 - 362 (2007/10/12)
Trifluoromethylsulfinate esters and trifluoromethylsulfinamides result when trifluoromethylsulfinyl fluoride reacts with alcohols and amines. Mercaptans with CF3S(O)F do not yield the expected thiosulfinates but rather mixed disulfides. The methylene protons of CF3CH2OS(O)CF3 and CH3CH2OS(O)CF3 are magnetically nonequivalent giving rise to ABM3X3 nmr spectra. The new compounds CF3S(O)OCH3, CF3S(O)OCH2CH3, CF3S(O)OCH2CF3, CF3S(O)N(CH2CH3)2, CF3S(O)N(CH3)2, (CF3S(O))2NCH3, and CF3S(O)NH2 are slightly volatile, colorless liquids.
