69173-79-1

Basic information

• Product Name: 4-nitro-N-[(E)-phenylmethylidene]aniline
• Synonyms: 4-nitro-N-[(1E)-phenylmethylene]aniline; 4-Nitro-N-[(E)-phenylmethylene]aniline; Benzenamine, 4-nitro-N-(phenylmethylene)-; benzenamine, 4-nitro-N-[(1E)-phenylmethylene]-; Benzylidene-(4-nitrophenyl)-amine
• CAS NO: 69173-79-1
• Molecular Formula: C₁₃H₁₀N₂O₃
• Molecular Weight: 226.2307
• Mol File: 69173-79-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 399.6°C at 760 mmHg
• Flash Point: 195.5°C
• Density: 1.16g/cm³
• Vapor Pressure: 3.12E-06mmHg at 25°C
• Refractive Index: 1.593
• CAS DataBase Reference: 4-nitro-N-[(E)-phenylmethylidene]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-nitro-N-[(E)-phenylmethylidene]aniline(69173-79-1)
• EPA Substance Registry System: 4-nitro-N-[(E)-phenylmethylidene]aniline(69173-79-1)

Safety Data

• Hazardous Substances Data: 69173-79-1(Hazardous Substances Data)

Upstream product

• 4485-08-9 4-nitrosonitrobenzene 
• 66045-11-2 aci-nitromethyl-benzene; potassium-compound 
• 16169-16-7 4-Nitro-N-phenylhydroxylamine 
• 100-52-7 benzaldehyde 

Downstream Products

• 68296-28-6 3ξ-(4-nitro-phenyl)-2,5-diphenyl-(3ar,6ac)-tetrahydro-pyrrolo[3,4-d]isoxazole-4,6-dione 

Relevant articles and documents

A novel general method for the synthesis of nitrones by reaction of nitroso compounds with anions of aliphatic nitro compounds

Anions of aliphatic nitro compounds R1R2C=NO2- react with nitroso compounds RNO to give nitrones R1R2C=N(O)R. Salts of nitro compounds with metals and Et3N, as well as trimethylsilyl nitronates in the presence of F-, can serve as the sources of the anions. The structure of the nitrones was established by NMR spectroscopy. 1,3-Dipolar cycloaddition of a series of the nitrones obtained to olefins was investigated.

13C and 1H NMR of Arylnitrones. Substituent Effects of α-Phenyl-N-(p-substituted phenyl)nitrones

Substituent effects on the chemical shifts of the conjugation sites in α-phenyl-N-arylnitrones (2) have been investigated.Resonance effects predominate at these positions.The electronic effects of the substituents should be treated separately between electron-donating groups and electron-donating groups and electron-withdrawing ones.A plausible mechanism for the transmission of substituent effects in 2 has been proposed.