692-99-9

Upstream product

• 1768-24-7 Cyansaeure-n-butylester 
• 333-20-0 potassium thioacyanate 
• 71-36-3 butan-1-ol 
• 871-58-9 potassium butylxanthate 
• 802028-88-2 hydrazinecarbothioic acid O-butyl ester 

Downstream Products

• 1313593-22-4 C₁₆H₂₅NO₃S₂ 
• 1415231-54-7 C₁₄H₂₁NO₃S₂ 
• 1415231-55-8 C₂₀H₂₅NO₃S₂ 
• 1400685-08-6 C₁₆H₂₁NO₂S 
• 17425-14-8 O-butyl N-phenylcarbamothioate 
• 19968-35-5 5-(3,4-dichloro-phenylsulfanyl)-4-methyl-3H-thiazol-2-one 
• 19968-32-2 5-(4-chloro-phenylsulfanyl)-4-methyl-3H-thiazol-2-one 
• 19968-36-6 5-(4-chloro-phenylsulfanyl)-4-phenyl-3H-thiazol-2-one 
• 19968-33-3 5-(2,4-dichloro-phenylsulfanyl)-4-methyl-3H-thiazol-2-one 
• 19968-37-7 5-(2,4-dichloro-phenylsulfanyl)-4-phenyl-3H-thiazol-2-one 
• 19968-39-9 5-(3,4-dichloro-phenylsulfanyl)-4-phenyl-3H-thiazol-2-one 
• 19968-41-3 4-(4-chloro-phenyl)-5-(4-chloro-phenylsulfanyl)-3H-thiazol-2-one 

Relevant academic research and scientific papers

An Fe3O4@SiO2/Schiff base/Cu(ii) complex as an efficient recyclable magnetic nanocatalyst for selective mono: N-arylation of primary O-alkyl thiocarbamates and primary O-alkyl carbamates with aryl halides and arylboronic acids

An efficient, convenient and novel method for the selective mono N-arylation of primary O-alkyl thiocarbamates and primary O-alkyl carbamates with aryl halides and arylboronic acids in the presence of a recyclable magnetic Cu(ii) nanocatalyst is described. A variety of mono N-arylated O-alkyl thiocarbamates and O-alkyl carbamates were prepared in good to excellent yields with a broad range of aryl coupling partners. The magnetic nanocatalyst can be easily recovered with an external magnetic field and reused at least five times without noticeable leaching or loss of its catalytic activity. This cost-effective and eco-friendly methodology has some other advantages, such as easy preparation of the catalyst, simple workup procedure, and easy purification, which makes this protocol interesting for the users in various fields of pharmacology and biotechnology systems.

Synthesis of primary thiocarbamates by silica sulfuric acid as effective reagent under solid-state and solution conditions

A simple and efficient method for the conversion of alcohols and phenols to primary O-thiocarbamates and S-thiocarbamates in the absence of solvent (solvent-free condition) using silica sulfuric acid (SiO2OSO 3H) as a solid acid is described. The products are easily distinguished by IR, NMR and X-ray data. X-ray data of the compounds reveal a planar trigonal orientation of the NH2 nitrogen atom with the partial C,N double-bond character and the CS or CO groups in synperiplanar position with CarylO and CalkylS moieties, respectively. Moreover, the OCSNH2 group which is perpendicular to the plane of the benzene ring in 1c and the central thiocarbamate SCONH2 group in 2b are essentially planar.

Hairpin folding behavior of mixed α/β-peptides in aqueous solution

The invention of new strategies for the design of protein-mimetic oligomers that manifest the folding encoded in natural amino acid sequences is a significant challenge. In contrast to the α-helix, mimicry of protein β-sheets is less understood. We report