69240-09-1

Upstream product

• 20113-43-3 1,2,3,4-tetra-O-acetyl-6-O-p-tolylsulfonyl-α-D-glucopyranose 
• 23661-33-8 methyl 2,3,4-tri-O-acetyl-6-O-(p-tolylsulfonyl)-α-D-glucopyranoside 
• 59202-80-1 Acetic acid (2R,3R,4S,5R)-4,5-diacetoxy-6-bromo-2-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-3-yl ester 

Downstream Products

• 73143-50-7 Acetic acid (2S,3R,5S,6R)-5-acetoxy-2-[(1S,2R,4R)-2,4-bis-(toluene-4-sulfonyloxy)-cyclohexyloxy]-6-(toluene-4-sulfonyloxymethyl)-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

The synthesis of various 1,6-disulfide-B ridged D-hexopyranoses

1,6-Disulfide-bridged derivatives have been prepared for D-gluco-, D-manno-, D-allo-, D-galacto-, and D-talopyranose, in the main by the nucleophilic attack of a C6 thiolate onto an anomeric thiosulfonate. The D-gluco disulfide, 'angyalosan', was successfully oxidized to a single thiosulfinate. CSIRO 2005.