6925-73-1

Basic information

• Product Name: but-2-enyl 1-methylallyl ether
• CAS NO: 6925-73-1
• Molecular Weight: 126.199
• Mol File: 6925-73-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: but-2-enyl 1-methylallyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: but-2-enyl 1-methylallyl ether(6925-73-1)
• EPA Substance Registry System: but-2-enyl 1-methylallyl ether(6925-73-1)

Safety Data

• Hazardous Substances Data: 6925-73-1(Hazardous Substances Data)

Upstream product

• 598-32-3 2-hydroxy-3-butene 
• 504-61-0 (E)-but-2-enol 
• 76-03-9 trichloroacetic acid 
• 4894-61-5 trans-but-2-enyl chloride 

Downstream Products

• 35194-31-1 6-octen-2-one 

Relevant articles and documents

1,2- and 1,5-Stereocontrols in 5-Hexenyl Radical Cyclizations: Cooperative or Antagonist Effect. Conformation Experimental Results with MM2 Calculations of Transition States

The cyclofunctionalization of 1,6-dienes 1 and 2 via the addition of tosyl radical allows the analysis of the combined effects of 1,2- and 1,5-stereocontrols on the outcome of 5-hexenyl radical cyclizations.MM2 calculations of the transition states agree quite well with the experimental selectivity, i.e., exclusive 1,2-trans control, and predominance of 1,5-cis over 1,5-trans relationship.The addition of TsBr to carbohydrate-derived epimeric dienes 3a and 3b shows that the stereochemistry of the newly formed C-C bond is controlled by the configuration of the C2 center of the radical. 1,5-trans or 1,5-cis selectivity can be achieved depending on the configuration of C2.