69257-71-2

Usage

InChI:InChI=1/C13H16O2/c1-15-13(10-6-5-9-12(13)14)11-7-3-2-4-8-11/h2-4,7-8H,5-6,9-10H2,1H3

Upstream product

• 67-56-1 methanol 
• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 5775-23-5 1-phenylcyclohexene oxide 
• 69257-64-3 2-methoxy-2-phenylcyclohexanol 

Downstream Products

• 1070898-72-4 di-tert-butyl 1-(2-oxo-1-phenylcyclohexyl)hydrazine-1,2-dicarboxylate 
• 1444-65-1 (2S)-2-phenyl-1-cyclohexanone 
• 34281-93-1 (R)-2-phenylcyclohexanone 

Relevant academic research and scientific papers

Enantioselective protonation of samarium enolates derived from α- heterosubstituted ketones and lactone by SmI2-mediated reduction

SmI2-mediated reductive cleavage of α-heterosubstituents of α-alkyl or α-aryl ketones and lactone gave the corresponding 'thermodynamic samarium enolates'. Enantioselective protonation of the samarium enolates with C2- symmetric chiral diols afforded the corresponding ketones and lactone in moderate to high enantioselectivities.

α-Oxidation of ketones using n-cation radicals

Six-membered ring ketones and acyclic ketones were oxidized by stable triarylamminium radical cations in moist acetonitrile at room temperature in the presence of a base to α-hydroxy ketones in good yield. Five-membered ring ketones gave the corresponding αβ-unsaturated compounds.